Enhancement of the polydimethylsiloxane (PDMS) luminescence to develop a proton scintillator

The polydimethylsiloxane (PDMS) luminescence, induced by MeV proton beams, has been investigated in the pure and doped polymer. Gold nanoparticles (AuNPs) and graphene oxide microparticles (GOμPs) have been employed at low concentration (0.1 wt%) to modify the PDMS properties. Measurements have demonstrated that AuNPs enhance the PDMS luminescence, while GOμPs quench the polymer luminescence. The first ones, embedded into PDMS, produce a visible luminescence whose intensity is proportional to the absorbed proton dose. A linearity between the luminescence intensity and the proton absorbed dose is observed up to about 2.5 kGy, while at higher doses a luminescence saturation region shows up. The polymer can be employed to monitor in vacuum the proton beam spot size and shape and as a plastic scintillator dosimeter with peculiar elastic properties and high biocompatibility, as it will be presented and discussed.